Materials: sheet of copper flashing
(1/2 sq. ft.), 2 alligator clips, micro-ammeter (read 10-50 mutlimeters),
electric stove (to temper copper), large clear plastic bottle, table
salt, sand paper on electric drill, tap water, sheet metal sheers
(to cut copper)
How it’s done:
Preparation:
Take the copper piece and cut a piece about the size of your stove’s
burner. Wash your hands and the piece of copper you cut thoroughly
so neither has any grease or oil on it. Now take the sand paper
to the copper sheet to remove any light corrosion or sulphide is
removed. Next, place the cleaned and dried copper sheet on the burner
and turn the burner to its highest setting. As the copper starts
to heat up, you will see beautiful oxidation patterns begin to form.
Oranges, purples, and reds will cover the copper. As the copper
gets hotter, the colors are replaced with a black coating of cupric
oxide. This is not the oxide we want, but it will flake off later,
showing the reds, oranges, pinks, and purples of the cuprous oxide
layer underneath. The last bits of color disappear as the burner
starts to glow red. When the burner is glowing red-hot, the sheet
of copper will be coated with a black cupric oxide coat. Let it
cook for a half an hour, so the black coating will be thick. This
is important, since a thick coating will flake off nicely, while
a thin coat will stay stuck to the copper. After the half hour of
cooking, turn off the burner. Leave the hot copper on the burner
to cool slowly. If you cool it too quickly, the black oxide will
stay stuck to the copper. As the copper cools, it shrinks. The black
cupric oxide also shrinks. But they shrink at different rates, which
makes the black cupric oxide flake off. The little black flakes
pop off the copper with enough force to make them fly a few inches.
This means a little more cleaning effort around the stove, but it
is fun to watch. When the copper has cooled to room temperature
(this takes about 20 minutes), most of the black oxide will be gone.
A light scrubbing with your hands under running water will remove
most of the small bits. Resist the temptation to remove all of the
black spots by hard scrubbing or by flexing the soft copper. This
might damage the delicate red cuprous oxide layer we need to make
to solar cell work.
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Cut another sheet of copper about the
same size as the first one. Bend both pieces gently, so they will
fit into the plastic bottle or jar without touching one another.
The cuprous oxide coating that was facing up on the burner is usually
the best side to face outwards in the jar, because it has the smoothest,
cleanest surface.
Attach the two alligator clip leads, one to the new copper plate,
and one to the cuprous oxide coated plate. Connect the lead from
the clean copper plate to the positive terminal of the meter. Connect
the lead from the cuprous oxide plate to the negative terminal of
the meter.
Now mix a couple tablespoons of salt into some hot tap water. Stir
the saltwater until all the salt is dissolved. Then carefully pour
the saltwater into the jar, being careful not to get the clip leads
wet. The saltwater should not completely cover the plates -- you
should leave about an inch of plate above the water, so you can
move the solar cell around without getting the clip leads wet.That’s
how it’s done.
Why it worksCuprous oxide is a type of material
called a semiconductor. A semiconductor is in between a conductor,
where electricity can flow freely, and an insulator, where electrons
are bound tightly to their atoms and do not flow freely.
In a semiconductor, there is a gap, called a bandgap between the
electrons that are bound tightly to the atom, and the electrons
that are farther from the atom, which can move freely and conduct
electricity.
Electrons cannot stay inside the bandgap. An electron cannot gain
just a little bit of energy and move away from the atom's nucleus
into the bandgap. An electron must gain enough energy to move farther
away from the nucleus, outside of the bandgap. Similarly, an electron
outside the bandgap cannot lose a little bit of energy and fall
just a little bit closer to the nucleus. It must lose enough energy
to fall past the bandgap into the area where electrons are allowed.
When sunlight hits the electrons in the cuprous oxide, some of the
electrons gain enough energy from the sunlight to jump past the
bandgap and become free to conduct electricity. The free electrons
move into the saltwater, then into the clean copper plate, into
the wire, through the meter, and back to the cuprous oxide plate.
As the electrons move through the meter, they perform the work needed
to move the needle. When a shadow falls on the solar cell, fewer
electrons move through the meter, and the needle dips back down.
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